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Ketamine is widely considered one of the safest drugs, so safe that only cops could find a way to overdose someone on it.
I didn't say it wasn't safe...
You're confusing the chemical science of things like LD50s of substances, with recommended medical practice by medical bodies such as which specific medicines are appropriate in which medical situations.
Again: there are dozens of medicines that would have been more appropriate than ketamine in this situation.
Why would those other medications be more appropriate. What's the problem with Ketamine in the first place?
This is a question best answered by an actual doctor or pharmacist. My line of reasoning is about established medical procedure, not the pharmacology or psychopharmacology of each possible medicine or substance that could be used in this situation.