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The main problem is that all the fossil fuel is carbon that has been trapped in a non-gaseous state (solid for coal, liquid for oil) for millions of years. Stuff that, under normal circumstances, would probably never get released back into the atmosphere.
So, for all intents and purposes, the only way to try and be carbon neutral is to offset your fossil fuel consumption. Not only trees, but also algae, which have a hard time thanks to all the shit we throw in the ocean, plus the overfishing. As others pointed, companies love throwing the term around to smoke their endless destruction in the name of FUCK TOMORROW, PROFITS NOW!