I make marine canvas. Sunbrella is a brand of exterior, water shedding fabric. Made of solution dyed acrylic and breathable to a degree. Off the roll it's quite stiff but softens up over time. They also make a line of exterior furniture fabric that has a much nicer hand. It would work for a cloak, not so much for a jacket.
As far as sewability, it depends on your machine and how many layers your design will cause you to sew through. A nice thing about it is it's two sided, there isn't a coating making a right and a wrong side.