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I like both, but usually prefer Ubuntu
(slrpnk.net)
I use Arch btw
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In principle yes, as Ubuntu is derived from Debian Sid, but with modifications to make it stable. Thus, the sources they are built from are different and hence, not completely binary compatible, like e.g. *Ubuntu and Mint or Debian and LMDE are. The configuration settings different also here and there and thus, guides for Ubuntu are not 1:1 transferable to Debian and vice versa.